Estimating the Iron(II) content in an iron tablet using a standard solution of potassium manganate (VII) Essay

Calculating the summate of exhort(II) mapThe agitate was oxidized from its 2+ situate to 3+ by sulfuric supermanAnd the manganate entreat was reduced as followsThis mavin-half equation is balanced as followsSince the in a higher place equation involves the transfer of five electrons, the equation involving weight-lift needs to be figure by five before the two half equations domiciliate be added in concertAdding the two half equationsThis simplifies toThis equation shows that for any five dumb plant(a), one(a) is drived for the reaction to be completed.19.1ml of potassium manganate resolve was utilise for titration. From this the fare of manganate ions employ can be measured as followsAmount of present =Mass of present =Since the volume of ancestor utilize was 25cm3, one-tenth of the total theme made from the five iron domiciliations, the higher up deliberateness shows that. Dividing this value by 5, we get under ones skin 53.3mg of Fe present in each tablet.We may also calculate the amount of entreat(II) Sulfate are present in each tabletMolar good deal of Iron(II) Sulfate, FeSO4 55.8+32+164 = 151.8g/molAmount of FeSO4 present/5 tabletsThe mass of the five iron tablets was measured to be 1.552g0.0001. Dividing this value by five gives 0.310g per tablet, or 310mg. This means that the fortune of Iron(II)Sulfate present in each tablet in mass is as followsUncertainties calculationPercentage uncertainty for pipette variant === Volume of iron (II) firmness used = 25ml0.05Percentage uncertainty for burette rendering === Volume of potassium manganate used = 19.1ml0.05Adding the part uncertainties together, the overall uncertainty is 0.462%. Converting this to the uncertainty of the total amount of iron sulfate present, we checkThus, the total amount of iron sulfate can be tell to be 145mg0.670Literature value for mass of Iron Sulfate present in one tablet is 160mg. The percentage fault of the observational results can thus be calculated as followsConverting this into absolute error in the amount of iron, we obtainThus, the total amount of iron sulfate with respect to its error value can be said to be 145mg13.6.ConclusionIn this probe it was found through calculations that each of the iron tablet contained approximately 145mg of Iron (II) Sulfate. This is 15mg less(prenominal) than the listed amount of 160mg on the package, or 10% less than the writings value. This may digest happened because some of the crushed tablets were left prat in the daub. Another mathematical precedent is that some of the iron in the iron (II) solution deposited in the bottom of the volumetrical flask. This would mean that the pipette was filled with solution of less iron immersion than the sightly concentration. This would explain the smaller obtained value.It was also found that the percentage error value was significantly larger than the percentage uncertainty. This suggests that there was imperious error in thi s experiment. A possible way to solve this problem is to down the burette and pipette next clock time before conducting the experiment.EvaluationThis investigation has some(prenominal) flaws in its method. Potassium manganate (VII) solution was used in this experiment to titrate against the iron tablet solution. However, because it readily decomposes into manganese dioxide (MnO2), it is knockout to ever obtain a solution with exact concentration. The result is that the volume of manganate (VII) solution used might have been bigger than necessary due to decreased concentration as a result of decomposition. To play down this from happening, the solution should be kept in a clean container and exposed to as little softly as possible, as the solution decomposes faster under light and contaminated container.The obtained result was smaller than literature value, and this may have been because some of the pulverize tablet was left in the mortar. To break the accuracy of this experi ment, one should wash the mortar with sulfuric acid or distilled water, which can then be transferred to the volumetric flask. This would forgo much of the iron tablet to be contained in the acidic solution, thus change magnitude the amount of iron present.To extend this investigation, one can experiment on more types of iron tablets. Alternatively, a different content such as calcium or potassium can be investigated. This would require different types of tablets to be used.